| 1. Personal |
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| Full Name |
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Arumugamangalam Venkataraman RAMASWAMY |
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| Date of birth |
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May 6, 1943 |
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| Place of birth |
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Thanjavur, Tamil Nadu, India |
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| Sex |
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Male |
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| Nationality |
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Indian |
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| Marital status |
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Married (wife: Dr. Mrs. Veda Ramaswamy) with two children (a daughter and a son) |
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| Present position |
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Chair Professor, National Centre for Catalysis Research, Indian Institute of Technology-Madras, Chennai - 600 036. Email: avram@chem.unipune.ernet.in , avram@eth.in |
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| 2. Education |
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Bachelor of Science in Chemistry, P.S.G. Arts College , Coimbatore , University of Madras (1963). |
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Master of Science in Chemistry, Loyola College , Madras , University of Madras (1965). |
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Ph.D. in Chemistry, Department of Chemistry, Loyola College , Madras , University of Madras (1969).
(Thesis title: "Catalytic transformation on Semiconductor Surfaces" Supervisor: Rev. Fr. Lourdu M. Yeddanapalli, S. J.) |
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Certificate Course in French, Alliance Français de Madras (1967). |
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Basic German language course (Gründstuffe), Max Mueller Bhavan, Madras (1968) and Goethe Institute, Schwabisch-Hall , Germany (1978) |
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| 3. Professional |
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| 1969 - 1972 |
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Lecturer, Loyola College ,
Madras 600 034. |
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| 1972 - 1989 |
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Scientist, Indian Institute of Petroleum,
Dehradun 248 005. |
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| 1989 – 2003 |
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Scientist, National Chemical Laboratory,
Pune 411 008. |
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| 1995 - 2003 |
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Head, Catalysis Division, National Chemical Laboratory, Pune 411 008
(Retired as Scientist G from NCL (CSIR) end of May 2003)
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| 2003 – 2006 |
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Emeritus Scientist (CSIR), Department of Chemistry, University of Pune , Pune 411 007 |
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| 2006 – |
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Chair Professor, NCCR, IIT-M, Chennai. |
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| 1978 –1979 |
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Post-doctoral Fellow (Alexander von Humboldt Foundation) Institute of Technical Chemistry I, University of Erlangen-Nürenberg, Erlangen, Germany. (Mentor: Prof. Dr. Hans Hoffman)
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| 4. Research Interests |
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Heterogeneous catalysis: development of catalysts for processes in petroleum refining, petrochemical, bulk chemical and fine chemical industries.
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Chemistry of catalytic processes: Catalytic reforming, hydrotreating, deep hydrodesulfurization, catalytic cracking, hydrocracking, hydrodewaxing and hydroisomerization.
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Selection and design of catalysts for different applications: The role of metal, support and promoters.
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Phenomenon of deactivation of catalysts: aging and catalyst poisons; regeneration of catalysts.
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Synthesis of catalysts and their characterization: influence of preparation parameters on the properties of catalysts; structural and textural characterization of catalysts; application of different spectral techniques for surface and bulk analysis; structure-property relationship in catalysis.
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Testing and screening of catalysts: Design of experiments in micro- and bench-scale reactors; optimization of reaction parameters; kinetics of catalytic reactions.
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Isomorphous substitution in zeolites: synthesis of novel metallo-silicate molecular sieves; location and environment of metal ions in zeolites and molecular sieves.
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Selective oxidation and hydroxylation of hydrocarbons for the synthesis of fine chemicals.
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Study of mixed metal oxides, condensed materials, perovskites, fluorites and spinels through novel methods of preparation and characterization.
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Exhaust emission control catalysts: total oxidation of hydrocarbons and carbon monoxide; deNOx reactions; three-way catalytic converters for automotive applications.
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Pillared-clays: intercalation of pillaring precursors, stability of PILCs, and catalytic applications.
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New Materials- Synthesis and Characterization.
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| 5. Achievements |
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- Development of mono- and bimetallic reforming catalysts for octane improvement and aromatic production (Catalyst commercialized).
- Deactivation of industrial catalysts in hydroprocessing. Contribution to petroleum refining industry on the estimation of catalyst life.
- Amorphous and Zeolite-based catalysts in hydrocracking of VGO. Catalyst formulation for maximizing middle distillates.
- Ferric molybdate - molybdenum trioxide catalyst for methanol to formaldehyde (Catalyst commercialized ).
- Perovskite and fluorite-based catalysts for total oxidation of hydrocarbons and
- Carbon monoxide for possible application in exhaust emission control.
- Stabilized Cu-silica catalyst for dehydrogenation of secondary alcohols to ketones. (Catalyst commercialized).
- Modified medium pore zeolite catalyst for isomerization of chloroaromatics. (Catalyst commercialized).
- Development of 3-way catalytic converter for 4-stroke engined vehicles conforming to Euro-2 and Euro-3 norms under Indian driving cycle (Under field trials).
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| 6. Current Interest and Activities |
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My current interest in the academic institution centers on synthesis of novel materials through some new techniques, which are unconventional. Some ceria and zirconia-based materials, and with metal incorporated in them have been synthesized and characterized for long range and short range orders in these materials by a variety of techniques. Possible applications of such materials include sensors, electrodes and catalysis for environmental benefits including photocatalysis.
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Teaching courses on homogeneous and heterogeneous catalysis (3 rd and 4 th semester) of M.Sc. (Inorganic Chemistry) at the Department. These courses have been devised to suit the present syllabus and to give the students a feel for the application of organo-metallics as catalysts in industrial homogeneous catalytic processes. Materials chemistry includes detailed exposure to porous materials in general and zeolites in particular. The final semester deals with a course on zeolites and application of zeolites and porous materials in heterogeneous catalysis.
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A member of the faculty for winter/summer schools on catalysis and orientation programs for research scholars in Catalysis (three-week courses) sponsored by the Department of Science and Technology, New Delhi at different centers in the country for the last 5 years.
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| 7. Memberships |
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- Founder - Life Member, The Catalysis Society of India (1974).
- Member, International Zeolite Association (1992).
- Member, Council of the International Congress on Catalysis (1988-1992).
- Founder Member, Indo-Pacific Catalysis Association (1996).
- Secretary, Indo-Pacific Catalysis Association (1998-2001).
- Life Member, Chemical Research Society of India (1999).
- Vice-President, Indo-Pacific Catalysis Association (2001-2003).
- President, The Catalysis Society of India (2001-2003).
- Member, Council of International Congress on Catalysis (2001-2004).
- Co-Chair, Organizing Committee, 14 International Zeolite Conference, Cape Town , South Africa (2004).
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| 8. Honours |
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Alexander von Humboldt Foundation Fellow (1978-79).
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CSIR Technology Award for commercialization of Bimetallic reforming catalyst (1992).
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ICICI Technology of the Year Award for commercialization of a catalyst for methanol to formaldehyde (1994).
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ICICI Technology of the Year Award for commercialization of a catalyst for the isomerization of chloroaromatics (2002).
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Member, Program Advisory Committee (Physical Chemistry) of Department of Science and Technology, New Delhi (1999-2001 and 2004-2007)
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Prof. R.A. Rajadhyaksha Lectureship, University Department of Chemical Technology, University of Bombay , Mumbai (2000).
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Member, Editorial Board of Eurasian Chemico-Technological Journal, Pub. Academy of Sciences , Almaty , Kazakhstan (2000-2004).
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Member, Editorial Board of Applied Catalysis A: General, Pub. Elsevier, Amsterdam , The Netherlands (2001-2003).
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Leader of Indian Delegation to First Indo-Kazakhstan Workshop on Catalysis, Almaty , Kazakhstan (2000).
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Member, Program Advisory Committee (Chemistry and Catalysis), International Collaborations, Department of Science and Technology, New Delhi (2001-2003).
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Leader of Indian Delegation to Indo-Hungarian Workshop on Surface Chemistry and Catalysis on Nanoparticles, Budapest , Hungary (2003).
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Member, Editorial Board of the Bulletin of the Catalysis Society of India. Vice-President, Humboldt Academy of Pune, Pune (2005-2007)
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| 9. Publications |
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| Number of Publications |
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135 |
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| Number of papers presented in conferences |
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40 |
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| Number of patents ( USA ) |
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Granted: 8, Filed: 5 |
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| Number of patents ( India ) |
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Granted: 10, Filed: 25 |
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| Number of invited talks, keynote lectures |
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25 |
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| Editor, Special Issue of Journal of Molecular Catalysis, A: Chemical (Elsevier, Amsterdam ) |
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Vol. 181 (2002) |
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| Editor, A book entitled "Catalysis: Principles and Applications" |
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Pub. Narosa Publishing House, New Delhi , 2002 |
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| Dr. A.V. Ramaswamy / Publications |
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Sl. No.
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Year
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Title
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Authors
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Journal
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1.
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2006
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Direct Hydrothermal Synthesis of Mesoporous Sn-SBA-15 Materials under Weak Acidic Conditions |
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P. Shah, A.V. Ramaswamy, K. Lazar V. Ramaswamy
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J.Phys.Chem.B (submitted, June 2006)
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2.
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2006
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Defect site promoted surface re-organization in nanocrystalline ceria for the low temperature activation of ethylbenzene |
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B. Murugan, A.V. Ramaswamy
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J. Am.Chem.Soc., (submitted, May 2006)
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3.
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d>
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4.
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2006
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Nanocrystalline ceria enriched with defect sites and its catalytic activity in oxidative dehydrogenation of ethylbenzene using N2O |
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B. Murugan,
A.V. Ramaswamy,
C.V. Satyanarayan
V. Ramaswamy
D. Srinivas |
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Chemistry of Materials (submitted, March 2006) |
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5.
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2006
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Au-Pt Nanoparticles in amine-functionalized MCM-41: Catalytic evaluation in hydrogenation reaction |
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T. Joseph,
Vijay Kumar. K, A.V. Ramaswamy, S.B. Halligudi
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Catalysis Communications, (in press)
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6.
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2006
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Epoxidation of indene and cyclooctene on nanocrystalline anatase titania catalyst |
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V. Ramaswamy,
P. Awati
A.V. Ramaswamy |
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Topics in Catalysis, 38. |
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7.
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2005
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Improving the quality of petroleum fuels through catalysis.
A chapter in "Catalysis in Petroleum and Petrochemical Industries" [Eds. K.G. Bhattacharyya and A.K. Talukdar] |
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A.V. Ramaswamy |
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Pub. Narosa Publishing House, New Delhi
pp. 42-52
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8.
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2005
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Influence of Sn- and Al-metal sources on post-synthesis modification of mesoporous SBA-15 molecular sieves
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P. Shah, A.V. Ramaswamy V. Ramaswamy
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Studies in Surface Science and Catalysis , 158A , 565-572 |
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9.
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2005
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Nature of manganese species in Ce1-xMnxO2-δ solid solutions synthesized by the solution combustion route
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B. Murugan, A.V. Ramaswamy, D. Srinivas, C.S. Gopinath, V. Ramaswamy
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Chemistry of Materials, 17, 3983-3993
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10.
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2005
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Oxidation of norbornene over vanadium-substituted phosphomolybdic acid catalysts and spectroscopic investigations
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N.K. Kalaraj, A.V. Ramaswamy, P. Manikandan
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Journal of Molecular Catalysis, A: Chemical, 227, 37-45
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11.
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2004
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Incorporation of tin into mesoporous silica SBA-15 molecular sieves
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P. Shah, A.V. Ramaswamy, R. Pasricha, K. Lazar, V. Ramaswamy
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Studies in Surface Science and Catalysis, 154 A , 870-877
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12.
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2004
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Structural and spectral features of nano-crystalline copper-stabilized zirconia
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V. Ramaswamy, M. Bhagwat, D. Srinivas, A.V. Ramaswamy
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Catalysis Today, 97 ,
63-70
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13.
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2004
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Synthesis and characterization of tin-oxide modified mesoporous SBA-15 molecular sieves and catalytic acivity in trans-esterification reaction
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P.Shah,
A.V. Ramaswamy,
K. Lazar,
V. Ramaswamy |
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Applied Catalysis A: General, 273, 239-248 |
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14.
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2004
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Reforming of n-hexane over Pt-Tin Silicalite-1 |
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N.K. Mal,
M.Sasidharan,
M. Matsukata,
S. Sivasanker,
A.V. Ramaswamy |
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Studies in Surface Science and Catalysis, 154 C, 2403-2410 |
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15.
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2003
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Selective oxidation of limonene over sodium salt of cobalt-containing sandwitch-type polyoxotungstate, [WCo3(H2O)2{W9CoO34}2]10-
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N.K. Kalaraj,
V.G. Puranik,
C. Gopinathan,
A.V. Ramaswamy |
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Applied Catalysis A: General, 256 , 265-273 |
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16.
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2003
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Rietveld refinement study of nanocrystalline copper doped zirconia |
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M. Bhagwat,
A.V. Ramaswamy,
A.K. Tyagi,
V. Ramaswamy |
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Materials Research Bulletin, 38 , 1713-1724 |
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17.
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2003
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Catalysts Selectivity: Shape-selective catalysis over zeolites
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A.V. Ramaswamy |
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Bulletin of the Catalysis Society of India 2 , 140-156
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18.
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2003
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Decomposition of NO and N2O on Cu-AlTS-1: Oscillatory behaviour at full N2O conversion
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Z. Schay,
L.Guczi,
G. Pal-Borbely,
A.V. Ramaswamy |
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Catalysis Today, 84, 165-171 |
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19.
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2003
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Catalysis research in India and the role of Catalysis Society of India
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A.V. Ramaswamy,
S. Sivasanker |
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Catalysis Surveys from Asia , 7, 91-94 |
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20.
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2002
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n-Hexane aromatization over Pt-tin silicalite molecular sieves
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N.K. Mal,
S. Sivasanker,
A.V. Ramaswamy |
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Bulletin of the Catalysis Society of India , 1, 121- |
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21.
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2002
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DeNOx reactions on Cu-zeolites: Decomposition of NO, N2O and SCR of NO by C3H8 and CH4 on Cu-ZSM-5 and Cu-AlTS-1 catalysts
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Z. Schay, L.Guczi, Beck, I. Nagy,
V. Samuel, S.P.Mirajkar, A.V.Ramaswamy, G. Pal-Borbely |
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Catalysis Today, 75, 393-399 |
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22.
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2002
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Shape-selective alkylation of 2-methoxynaphthalene with tert-butanol over large-pore zeolites |
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N.Srinivas, A.P. Singh, A.V. Ramaswamy, Finiels, P. Moreau |
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Catalysis Letters, 80, 181-186 |
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23.
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2002
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Photoemission studies of polymorphic CaCO3 materials |
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C.S.Gopinath,
S.G. Hegde,
A.V. Ramaswamy,
S. Mahapatra |
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Materials Research Bulletin, 37, 1323-1332 |
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24.
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2002
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A novel single step selective synthesis of
4-hydroxybenzophenone (4-HBP) using zeolite H-beta |
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V.D. Chaube,
P. Moreau, Finiels, A.V. Ramaswamy, A.P.Singh |
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Catalysis Letters, 79, 89-94 |
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25.
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2002
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Immobilization and characterization of copper chlorophthalocyanine on alumina-pillared montmorillonite |
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V. Ramaswamy,
M.S. Krishnan,
A.V. Ramaswamy |
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Journal of Molecular Catalysis A: Chemical, 181 , 81-89 |
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26.
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2002
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Acylation of alcohols, thiols and amines with carboxylic acids catalyzed by yttria-zirconia-based Lewis acid |
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P. Kumar,
R.K.Pandey,
M.S. Bodas,
S.P. Dagade,
M.K. Dongare
A.V. Ramaswamy |
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Journal of Molecular Catalysis A: Chemical, 181 , 207-213 |
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27.
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2002
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Selective benzoylation of biphenyl to 4-phenylbenzophenone over zeolite H-beta |
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M. Chidambaram,
Venkatesan,
P. Moreau, Finiels,
A.V. Ramaswamy,
A.P. Singh |
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Applied Catalysis A: General, 224 , 129-140 |
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28.
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2002
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Structure and redox properties of Cu in cubic copper-zirconia catalysts:
An EPR investigation |
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D.Srinivas, Ebenezer,
M.K. Dongare,
A.V. Ramaswamy |
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Bulletin of the Catalysis Society of India , 1. |
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29.
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2002
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Textural Characterization of Catalysts, Chapter 4, in "Catalysis: Principles and Applications" [Eds. B.Viswanathan, S.Sivasanker and A.V. Ramaswamy] |
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A.V. Ramaswamy |
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Pub. Narosa Pub. House, New Delhi, 48-69 |
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30.
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2002
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Catalysis and Theoretical Concepts, Chapter 12, in "Catalysis: Principles and Applications" [Eds. B.Viswanathan, S. Sivasanker and A.V. Ramaswamy] |
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A.V. Ramaswamy |
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Pub. Narosa Pub. House, New Delhi, 206-219 |
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31.
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2002
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Catalysis and Production of Petrochemicals Chapter 16, in "Catalysis: Principles and Applications" [Eds. B.Viswanathan, S.Sivasanker and A.V. Ramaswamy] |
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A.V. Ramaswamy |
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Pub. Narosa Pub. House, New Delhi, 243-252 |
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32.
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2001
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Acidity and m-xylene isomerization activity of large-pore, zirconium-containing alumino-silicate with BEA structure |
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A.V. Ramaswamy, Rakshe,
V. Ramaswamy |
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Journal of Catalysis, 188, 252-260 |
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33.
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34.
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2001
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Oxidation activity and 18O-isotope exchange behaviour of Cu-stabilized cubic zirconia |
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M.K. Dongare,
V. Ramaswamy,
C.S. Gopinath,
A.V. Ramaswamy,
S. Scheurell,
M. Brueckner,
E. Kemnitz |
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Journal of Catalysis, 199 , 209-216 |
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35.
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2001
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Propionylation of phenol to 4-hydroxy-propiophenone over zeolite H-beta |
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V.D.Chaube,
P. Moreau,
Finiels,
A.V. Ramaswamy,
A.P. Singh |
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Journal of Molecular Catalysis, A: Chemical, 174, 255-264 |
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36.
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2001
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Liquid phase selective benzoylation of chlorobenzene to 4,4'-dichloro-benzophenone over zeolite H-beta |
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Venkatesan,
T. Jaimol,
P. Moreau,
Finiels,
A.V. Ramaswamy,
A.P. Singh |
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Catalysis Letters, 75, 119-123 |
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37.
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2001
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Selective propionylation of veratrole to
3,4-dimethoxypropiophenone using zeolite H-beta catalysts
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T. Jaimol,
P. Moreau, Finiels, A.V. Ramaswamy, A.P. Singh
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Applied Catalysis A: General, 214 , 1-10 |
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38.
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2001
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Benzoylation of 1,2-dimethoxybenzene with benzoic anhydride and substituted benzoyl chloride over large pore zeolites
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T.Raja, A.P. Singh, A.V. Ramaswamy, Finiels, P. Moreau
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Applied Catalysis A: General, 211 , 31-39
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39.
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2000
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Decomposition and selective catalytic reduction of NO by propane on CuZSM-5
zeolites: A mechanistic study |
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Z. Schay,
V.S. James, G. Pal-Borbely, A. Beck, A.V. Ramaswamy, L. Guczi
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Journal of Molecular Catalysis A: Chemical, 162 , 191-198
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40.
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2000
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Factors affecting the preparation of alumina pillared montmorillonite employing ultrasonics
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S.P. Katdare,
V. Ramaswamy A.V. Ramaswamy
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Microporous and Mesoporous Materials, 37, 329-336
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41.
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2000
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Valency changes of iron and tin in framework-substituted molecular sieves investigated by in-situ Mössbauer spectroscopy |
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K. Lazar, A.J. Chandwadkar, P. Fejes, J. Cejka, A.V. Ramaswamy
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Journal of Radioanalytical and Nuclear Chemistry, 246 , 143-148
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42.
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2000
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Insights into the formation of hydroxyl ions in calcium carbonate: Temperature dependent FTIR and molecular modeling studies
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S.I. Kuriyavar,
R. Vetrivel,
S.G. Hegde,
A.V. Ramaswamy, Chakrabarty,
S. Mahapatra
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Journal of Materials Chemistry, 10, 1835-1840
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43.
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2000
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Clays, Zeolites and Solid Acid Catalysts |
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A.V. Ramaswamy |
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Chimica & Industria
( Milan ), 82 (6), E1-9
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44.
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2000
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Preparation of alumina-pillared montmorillonite clays employing ultrasonics and their catalytic properties |
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S.P. Katdate, V. Ramaswamy, A.V. Ramaswamy
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Eurasian Chemico- Technological Journal, 2, 53-58
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45.
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2000
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Enhanced para-selectivity in alkylation and isomerization reactions over silynated ZSM-5 zeolite Chapter 15, in "Shape Selective Catalysis" [Eds. C. Song, J.M. Garces and Y. Sugi]
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B.S. Rao,
R.A. Shaikh, A.V. Ramaswamy
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ACS Symposium Series, 738, Pub. American Chemical Society, 225-235
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